How the Periodic Table Almost Wasn't Mendeleev's

Mendeleev was not the first chemist to notice that elements repeat in patterns. Here is why his 1869 table won out over at least three earlier attempts.

Dmitri Mendeleev's Big Idea, illustrated

On March 6, 1869, Russian chemist Dmitri Mendeleev presented a paper to the Russian Chemical Society titled "The Dependence Between the Properties of the Atomic Weights of the Elements." He had arranged the sixty-three known chemical elements by atomic weight into rows, breaking each row so that elements with similar chemical behavior lined up in the same columns. Where the pattern called for an element nobody had yet found, he did not force the row to close up — he left the space blank and described, in advance, what should eventually fill it.

That table is the one still hanging in classrooms today. But Mendeleev was not the first chemist to notice that elements repeat their properties at regular intervals, and he was not even the only person publishing a periodic arrangement in his own decade. At least three other chemists had gotten there first, or nearly at the same time — and history remembers only one of their tables.

The chemists who saw the pattern before he did

As early as 1862, French geologist Alexandre-Émile Béguyer de Chancourtois plotted the known elements on a spiral by increasing atomic weight and noticed that similar elements lined up along the same vertical line — an early hint of periodicity that went largely unnoticed outside France. In 1865, English chemist John Newlands arranged elements in order of atomic weight and observed that every eighth element shared similar properties, a pattern he called the "law of octaves." Newlands even predicted an undiscovered element with an atomic weight of about 73 — six years before Mendeleev made a nearly identical prediction for the same gap. But Newlands left no blank spaces in his table for missing elements, and his idea was mocked by chemists of the day, one of whom reportedly asked, in a Chemical Society meeting, whether he had tried arranging the elements alphabetically instead.

What made Mendeleev's version different

The difference was not that Mendeleev saw a pattern nobody else had seen. It was that he trusted the pattern enough to bet against the existing inventory of known elements and say, in print, exactly where and by how much it was incomplete. He named the gaps in his table after the known element just above them — eka-aluminium, eka-boron, eka-silicon — and predicted their atomic weights and chemical behavior in specific, checkable detail. Within seventeen years, all three were found almost exactly where he said they would be: gallium in 1875, scandium in 1879, and germanium in 1886. Each discovery matched Mendeleev's predicted properties closely enough that his table went from a proposal to, effectively, settled science.

A rival table, and two very different receptions

German chemist Julius Lothar Meyer had been building his own versions of a periodic table since 1864 and published one strikingly similar to Mendeleev's in 1870, a year after Mendeleev's. Meyer's table also left gaps for undiscovered elements, but he did not predict what would fill them. The Royal Society of London eventually judged the two men's contributions close enough in importance to award its 1882 Davy Medal to both jointly. Newlands had to wait far longer for recognition: the Chemical Society dismissed his 1865 paper outright, and it was not until 1887 — twenty-two years later — that the Royal Society awarded him a Davy Medal of his own, and not until 1998 that his birthplace received an official commemorative plaque.


Told as an illustrated story

Dmitri Mendeleev's Big Idea — book cover — Illustrated Science Stories and Discoveries
Dmitri Mendeleev's Big Idea → Dmitri Mendeleev's story on Wonder Science

Frequently Asked Questions

Did Mendeleev invent the periodic table completely on his own?

No. Chemists including Alexandre-Émile Béguyer de Chancourtois, John Newlands and Julius Lothar Meyer had all noticed patterns in the properties of elements before or around the same time as Mendeleev. What set his 1869 table apart was his willingness to leave gaps for undiscovered elements and predict their exact properties in advance.

How did Mendeleev predict elements that hadn't been discovered yet?

He noticed that the properties of elements repeated in a regular pattern based on atomic weight. Where his table showed a gap in that pattern, he calculated what an element filling it should weigh and how it should behave chemically — predictions later confirmed almost exactly by the discoveries of gallium (1875), scandium (1879) and germanium (1886).

Why does Mendeleev get more credit than Newlands or Meyer?

Newlands published a similar idea in 1865 but left no gaps for missing elements and was dismissed by chemists of his time; he only received formal recognition, a Royal Society medal, in 1887. Meyer published an independent, similar table in 1870, a year after Mendeleev, and the two later shared a joint medal. Mendeleev is remembered as the primary discoverer mainly because his specific, testable predictions were the ones proven right.

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